Search results for "Transfer mechanism"
showing 10 items of 11 documents
Experimental and Computational Studies of Hydrogen Bonding and Proton Transfer to [Cp*Fe(dppe)H]
2005
The present contribution reports experimental and computational investigations of the interaction between [Cp*Fe(dppe)H] and different proton donors (HA). The focus is on the structure of the proton transfer intermediates and on the potential energy surface of the proton transfer leading to the dihydrogen complex [Cp*Fe(dppe)(H2)]+. With p-nitrophenol (PNP) a UV/Visible study provides evidence of the formation of the ion-pair stabilized by a hydrogen bond between the nonclassical cation [Cp*Fe(dppe)(H2)]+ and the homoconjugated anion ([AHA]-). With trifluoroacetic acid (TFA), the hydrogen-bonded ion pair containing the simple conjugate base (A-) in equilibrium with the free ions is observed…
Investigation of Effective Thermal Conductivity Aluminum Foams
2012
Abstract The study on the heat transfer mechanisms through the aluminium foam with a fluid in void cells of that foam was reported in this paper. Based on laboratory experiments, the effective thermal conductivity coefficient values were found for various type aluminum foams which had been filled up with a gas or a liquid. The significant effects were observed from porosity as well as from metal and fluid properties on the heat transfer capacity in a foam-fluid system. The convective heat transfer phenomenon was identified to occur in the foam cellular space. That phenomenon affected the effective thermal conductivity much more for liquid-filled foams than for gas-filled foams.
Submicellar and micellar reversed-phase liquid chromatographic modes applied to the separation of beta-blockers.
2009
The behaviour of a reversed-phase liquid chromatographic (RPLC) system (i.e. elution order, resolution and analysis time), used in the analysis of β-blockers with acetonitrile-water mobile phases, changes drastically upon addition of an anionic surfactant (sodium dodecyl sulphate, SDS). Surfactant monomers cover the alkyl-bonded phase in different extent depending on the concentration of both modifiers, in the ranges 1 × 10-3-0.15 M SDS and 5-50% acetonitrile. Meanwhile, the surfactant is dissolved in the mobile phase as free monomers, associated in small clusters or forming micelles. Four characteristic RPLC modes are yielded, with transition regions between them: hydro-organic, micellar, …
Stress transfer and failure mechanisms in steel-concrete trussed beams: Experimental investigation on slab-thick and full-thick beams
2018
Abstract This study presents the results of an experimental investigation on semi-precast Hybrid Steel Trussed-Concrete Beams (HSTCBs) for analyzing the failure modes and the stress transfer mechanism between concrete and embedded steel elements (plate and truss). The available literature presents previous studies carried out by the authors mainly focused on the understanding of the local transfer mechanism by means of push-out tests. Conversely, in this paper original the results of laboratory tests conducted on six specimens of full-size HSTCBs subjected to four-point bending, with variation in the shear span, are reported on. From these results, the authors are able to assess the failure…
Review of push-out and shear response of hybrid steel-trussed concrete beams
2018
The hybrid steel trussed concrete beams examined in the present study are comprised of two principal components, i.e., a steel joist with inclined rebars, realized in industry, which is welded to a smooth steel plate and then embedded within the concrete cast in situ. The paper presents first the state of the art on laboratory tests and analytical modeling of the steel-to-concrete stress transfer mechanism investigated by push-out tests. Next, the most relevant scientific contributions currently available in the technical literature regarding experimental investigation on actual shear behavior are summarized and discussed. Lastly codes and analytical models are reviewed.
Assessment of push-out test response of hybrid steel trussed-concrete beams by FE model
2013
Aiming to investigate the truss-concrete stress transfer mechanism in Hybrid Steel Trussed-Concrete Beams (HSTCBs), a three-dimensional nonlinear FE model is developed. The constitutive laws of the steel composing the plates and the bars is modeled by means of a quadri-linear law, while the concrete behavior is defined by means of a Concrete Damaged Plasticity (CDP) model, suitable for modeling concrete and brittle materials. The CDP model uses the concept of isotropic damaged elasticity in combination with isotropic tensile and compressive plasticity and is able to properly account for the concrete confinement effect. Two main failure mechanisms are considered, namely the tensile cracking …
How a Second Mg2+ Ion Affects the Phosphoryl-Transfer Mechanism in a Protein Kinase: A Computational Study
2020
Mg2+ ions are essential for the proper functioning of protein kinases, and their roles in kinase activity have been studied for years. However, recent investigations have shed light on how these me...
Analytical prediction of the shear connection capacity in composite steel–concrete trussed beams
2016
Steel–concrete trussed composite beams are a particular types of composite girders constituted by a steel truss embedded in a concrete core. The truss is typically composed by a steel plate or a precast concrete slab working as bottom chord while coupled rebars are generally used to form the upper chord. Moreover, a system of ribbed or smooth steel rebars welded to the plate and forming the diagonals of the truss, works as web reinforcement. In the present study, the attention is focused on the evaluation of the shear resistance of the connection between bottom steel plate (the bottom chord) and concrete core through the diagonal bars of the truss developing a mechanical model able to accou…
Does the EMU Need a Fiscal Transfer Mechanism?
2004
Summary: The aim of this paper is to investigate how the birth of a central fiscal authority or the creation of a fiscal transfer mechanism could improve the action of fiscal policy in terms of stabilization in the EMU. In particular, the paper examines the theoretical reasons to support this conclusion and provides empirical evidence that shows how the EMU is not able to face asymmetric and symmetric idiosyncratic shocks. Zusammenfassung: Die zentrale Frage des Aufsatzes lautet: Ob und wie kann eine zentrale Fiskalbehorde oder ein fiskalischer Transfermechanismus die fiskalpolitische Stabilisierung in der EWU verbessern? Dazu werden theoretische Argumente und empirische Evidenz prasentiert…
Stress transfer mechanism investigation in hybrid steel trussed-concrete beams by push-out tests
2014
Abstract Results of push-out tests carried out on Hybrid Steel Trussed–Concrete Beams (HSTCBs) before and after the concrete casting are presented and interpreted. Firstly, in order to check the ability of weldings before casting, tensile tests were performed on specimens reproducing different types of welded joints. Simplified design formulae were used to predict their ultimate strength. Secondly, results obtained by push-out tests on specimen representative of the beam before and after the concrete casting are presented and discussed. Finally, simplified analytical models proposed by the current European building code were adapted to the specific typology to roughly predict the ultimate s…